Many things could be going on here. How long have you owned this and how many miles on it? New to you and you are discovering why they sold it?
Pictures can help answer questions. First a picture of the fan clutch so we can see what kind you have. How old is the fan clutch? I ask as a "root cause" question.
Holding pressure is a good sign. I would suspect the radiator cap is having trouble. Pressure test it. I have had poor quality caps and radiators not release pressure, then blow off suddenly shock cooling the engine, and then suck the hoses flat. I have seen cracked heads tend to leak as the engine warms up and seal cold.
A failing water pump with a slipping or worn impeller or clogged radiator is a suspect.
If you can't get the air bled out of the system I would suggest you remove the fan belt(s) and the thermostat crossover. Then start the engine and look for bubbles coming out of the coolant head ports. IMO 2 - 5 min should be enough and keep in mind the difference between bubbles and boiling. Bubbles indicate combustion gas leaks from: head gasket, head cracks, cylinder cracks. Sometimes it's just one side and you can concentrate repairs on that one side.
Tabs (coolant stop leak) make a mess in the radiator and are designed as a cheap band aid to kick the problem can down the road. (Cracked heads or blown headgaskets, but, general coolant leaks are what most would try and cure.) They might get you home from a bad adventure where you 'caught one in the radiator' and emergency repairs to get home. Bad advice if you wish to fix it properly long term the first time. Worse they somewhat cover up the problem so you can't diagnose it as easy.
H1 Hummer owners can better comment on the ECT of 220-230 due to the radiatror angle making it difficult to cool. The military treats these engines as expendable thus don't care about turning rings to slag temps. From pickups and SUV's the upper limit is 210 back off - 220 pull over. Rings turn to blowby and cracks are more likely to appear at higher ECT than 210.